You need to interupt the behavior before it becomes obsessive. Push the 'humper' off the other dog by pushing on the 'humpers' shoulders. Hard enough to get him off, and startle him. At the same time, say, 'leave it' or 'no hump' or whatever.
Prior to mounting, there are usually quite a few signs. When he starts sniffing around the desired 'humpee' interupt this behavior. Call him to you, offer a toy, play with a ball, whatever. If he doesn't come when called, grab him and put him on a leash, and leave.
I can usually tell if my dog is overly interested in another dog by his body language (tail straight up, with a fixed, stiff type wag, head erect, stiff body posture). This is usually matched by the other dog. We meet at least 10-20 dogs on the trails we run each day, rarely (less than once a week) does interaction go beyond a quick sniff, play bow, or tail wag. If I see unwanted body language in either dog (mine or the dog on the trail), I command 'on-by' and make sure he complies. In most cases 'on-by' is understood, and I don't need to say it. In a dog park, you don't have this advantage of forward movement. You need to interupt the dominance progression before it starts. Learn to read your dog.
If you can't interupt the humping before it starts, teach your dog both 'up' and 'off'. (this is based on advice from one of my friends on the board- something I wouldn't have thought of on my own) 'Up' means the dog puts his front feet up on something, a desk, bench, trash can, playground equipment. 'Off' means back to all four feet on the group. My dog loved learning it, and I was able to teach this in one session of marker training. Then worked on distance with the off. This is the last resort command, though. Ideally, you interupt any humping progression before it starts.
Another thing to remember is that you need to be 100% convinced that this behavior is unacceptable and be totally committed to stopping it. He should never get a chance to self-fulfil his humping urges. I committed my self to never, ever allowing this behavior. It's not cute, funny, or cool- at all.
I'm nearly 100% sure you can control this behavior. I hope some of my sugggestions help. In some cases, the humping is an outlet for frustrated energy. Providing an alternative outlet (ball, tug, play time) and firm corrections for unwanted humping (push dog off, then leash and leave), might be all it takes.
Just my opinion, of course. Humping is not uncommon, and is actually fairly 'normal' dog behavior. But that doesn't matter. It is one of the dog behaviors that you have decided you won't allow. As the owner of a re-habbed occasional humper, I will tell you it is very possible to train a humper not to hump. I'd make 100% certain there are no female dogs in heat in the dog park, though. This is a huge distraction for any male dog. A 100% recall is a big plus, but, you need to work up slowly to this ultimate distraction (search the site for recall threads for more information on that).
One other thought. Certain disorders can cause increased sexual interest in male dogs. If the behavior is super obsessive, and he's doing it to chairs, stuffed animals, your leg- all of a sudden- you might want to consult a vet.
And a last question. Is he doing this to males or females? Male-male humping is usually dominance. Male-female could be either dominance or sexual interest but may be more indicative of some sort of hormonal issue- all just my thoughts.